Thermodynamics of organic azides: Experimental vapor pressures of organic polyazido compounds measured with the transpiration method
نویسندگان
چکیده
In this study experimental vapor pressures of several organic azides including 1,3-diazidopropan-2-ol (1,3-DAP, CAS: 57011-48-0), 2,3-diazidopropan-2-ol (2,3-DAP, 67880-10-8) and geminal diazido group containing 1,3‑diethyl-2,2-diazidomalonate (DE-DAM, 168207-98-5) were measured for the first time using transpiration method. The provides p-T fitting equations corresponding molar enthalpies vaporization, adjusted to 298.15 K: (72.6 ± 0.5) kJ mol−1 1,3-DAP, (75.2 0.6) 2,3-DAP (76.0 1.1) DE-DAM.
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ژورنال
عنوان ژورنال: Fluid Phase Equilibria
سال: 2021
ISSN: ['0378-3812', '1879-0224']
DOI: https://doi.org/10.1016/j.fluid.2021.113222